Entertainer of the Year nominee Faith Hill will perform her new single, "There Will Come a Day," Oct. 4 on the 34th annual Country Music Association Awards. Four-time CMA award-winner Kenny Rogers will perform his No. 1 hit and Single of the Year nominee, "Buy Me a Rose," in his first appearance on the show in 16 years. Others confirmed for the broadcast include nominees Lonestar (Vocal Group), SHeDAISY (Horizon) and Toby Keith (single, video). Keith will perform "How Do You Like Me Now?!," the song that brought the singer his first-ever CMA nominations. Male Vocalist nominee Vince Gill will host the event, broadcast live by CBS from 8 -11 p.m. ET at the Grand Ole Opry House.