Brad Paisley and Alison Krauss will perform their duet, "Whiskey Lullabye," Wednesday (May 26) during the Academy of Country Music Association Awards before appearing Sunday (May 30) at the National Memorial Day Concert in Washington, D.C. The concert on the west lawn of the U.S. Capitol will also include her band, Union Station, featuring Jerry Douglas. Actor and World War II veteran Ossie Davis hosts the event featuring classical violinist Joshua Bell and actors Tom Hanks, Joe Mantegna, Charles Durning and Jason Ritter. The Washington concert will be broadcast on PBS. CBS will telecast the ACM Awards.