Faith Hill and Keith Urban will appear together during a performance segment at the 48th annual Grammy Awards in Los Angeles. Hill is nominated for three Grammys, including best female country vocal performance ("Mississippi Girl"), best country collaboration with vocals ("Like We Never Loved at All" with Tim McGraw) and best country album (Fireflies). Urban's recording of "You'll Think of Me" is nominated for best male country vocal performance. No other country artists have been announced as performers. Big & Rich will present an award when the Grammy show airs live Feb. 8 on CBS.